First total synthesis of paracaseolide A.
نویسندگان
چکیده
The first total synthesis of the paracaseolide A, a very unusual tetraquinane oxa-cage bislactone recently isolated from the mangrove Sonneratia paracaseolaris, has been achieved. The final step and culmination of the eight-step synthetic sequence is a [4 + 2] dimerization of a 4-hydroxybutenolide, generated by singlet oxygen-mediated oxidation of a furan precursor.
منابع مشابه
Total synthesis of paracaseolide A.
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عنوان ژورنال:
- Organic letters
دوره 14 14 شماره
صفحات -
تاریخ انتشار 2012